It’s a bit complicated but the bottom line is that it won’t work like that.
The 6332 has the same electronic board as the ISS. The problem is that to get data from any of the other inputs, temp, solar etc. the 6332 station type must be set as “ISS” on the console. Since the system can only have one “ISS” you would lose the data from the original ISS.
https://www.davisinstruments.com/product_documents/weather/app_notes/AN_32-sensor-configurations.pdf